Polymer (Sheet) Polarizer

Model iodine-PVA sheet polarizers (H-sheet type): principal transmittances k₁ and k₂, extinction ratio and efficiency from the film's absorption, dichroic ratio and thickness.

Model: Exact

stretched PVA–iodine film: chains along the stretch absorb E ∥ stretch (α∥), pass E ⟂ (α⟂ = α∥/Rd)

k = (1 − R)² e−αd/(1 − R² e−2αd),  k₁ = k(α⟂) pass, k₂ = k(α∥) block

extinction k₁/k₂,  efficiency (k₁ − k₂)/(k₁ + k₂),  one sheet (k₁ + k₂)/2,  crossed pair k₁k₂

α is the natural-log (Napierian) absorption coefficient; a decadic absorbance A corresponds to αd = 2.303 A. One wavelength, normal incidence, uncoated faces in air. The defaults are illustrative, not a product's data.

k₁ (pass, E ⟂ stretch)

76.49 %

face reflectance 4.00 %

k₂ (block, E ∥ stretch)

5.10e-4

α∥d = 7.50

Extinction ratio k₁/k₂

31.8 dB

polarizing efficiency 99.8668 %

Unpolarized light

one sheet 38.3 %

parallel pair 29.3 %; crossed pair 3.90e-4

Principal transmittances against film thickness (log₁₀)

Extinction against pass transmittance as the film thickens

Model and references

Exact. The equations are exact within the stated assumptions, or are a standard's tabulated values. The results are as good as the inputs. About the tiers

Homogeneous film at one wavelength: Beer–Lambert absorption per axis (α∥ = R_d α⊥), face reflections, multiple reflections added in power. Not modelled: spectra, scattering, protective layers.

  1. Shurcliff W. A. (1962). Polarized Light: Production and Use, ch. 3 Polarizers: classes and performance parameters, pp. 32–42 (principal transmittances k₁, k₂). Harvard University Press. doi:10.4159/harvard.9780674424135.c4
  2. Shurcliff W. A. (1962). Polarized Light: Production and Use, ch. 4 Dichroic polarizers, pp. 43–64. Harvard University Press. doi:10.4159/harvard.9780674424135.c5
  3. Macleod H. A. (2010). Thin-Film Optical Filters, 4th ed., ch. 2 Basic Theory, pp. 13–71. CRC Press. doi:10.1201/9781420073034-c2
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